Electrochemical amination of unsaturated and aromatic compounds

Authors
Lisitsyn, YA Kargin, YM
Citation
Ya. Lisitsyn et Ym. Kargin, Electrochemical amination of unsaturated and aromatic compounds, RUSS J ELEC, 36(2), 2000, pp. 89-99
Citations number
57
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
RUSSIAN JOURNAL OF ELECTROCHEMISTRY
ISSN journal
10231935 → ACNP
Volume
36
Issue
2
Year of publication
2000
Pages
89 - 99
Database
ISI
SICI code
1023-1935(200002)36:2<89:EAOUAA>2.0.ZU;2-Z
Abstract
The mechanism and synthetic perspectives of an indirect cathodic amination of unsaturated and aromatic substrates are considered. The influence of exp erimental conditions on the state and reactivity of the aminating reagent i n solution is studied. The key role of the electrolyte acidity and redox pr operties of the reagents and intermediates in the obtained isomeric composi tion and the yield of the amination products is demonstrated.