Kinetics and mechanism of reaction of sodium arsenite with chloroacetic acid in aqueous alkalis

Authors
Rakhmatullin, RR Emelyushin, RE Gavrilov, VI
Citation
Rr. Rakhmatullin et al., Kinetics and mechanism of reaction of sodium arsenite with chloroacetic acid in aqueous alkalis, RUSS J G CH, 69(9), 1999, pp. 1389-1390
Citations number
3
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632 → ACNP
Volume
69
Issue
9
Year of publication
1999
Pages
1389 - 1390
Database
ISI
SICI code
1070-3632(199909)69:9<1389:KAMORO>2.0.ZU;2-H
Abstract
The Meyer reaction of sodium arsenite with chloroacetic acid in aqueous alk alis occurs by the SN2 mechanism and is accompanied by concurrent alkaline hydrolysis of chloroacetic acid; the rate constants and the activation ener gies and entropies of these reactions were determined.