(N-heterylmethyl)trimethoxy- and (N-heterylmethyl)dimethoxymethylsilanes

Citation
Nf. Chernov et al., (N-heterylmethyl)trimethoxy- and (N-heterylmethyl)dimethoxymethylsilanes, RUSS J G CH, 69(9), 1999, pp. 1398-1400
Citations number
9
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632 → ACNP
Volume
69
Issue
9
Year of publication
1999
Pages
1398 - 1400
Database
ISI
SICI code
1070-3632(199909)69:9<1398:(A(>2.0.ZU;2-3
Abstract
(Chloromethyl)trimethoxy- and (chloromethyl)dimethoxymethylsilane were reac ted with N-sodium salts of imidazole, 3,5-dimethylpyrazole, indole, benzimi dazole, and phthalimide to obtain the corresponding (N-heterylmethyl)trimet hoxy- and (N-heterylmethyl)dimethoxymethylsilanes. Trasetherification of (N -heterylmethyl)trimethoxysilanes with triethanolamine gave previously unkno wn 1-(N-heterylmethyl) silatranes. The first synthesis of poly(N-heterylmet hyl)silsesquioxanes was performed by hydrolysis of (N-heterylmethyl)trimeth oxysilanes.