Synthesis of alkyl-substituted 1,3-dioxolanes by catalytic dehydration of 1,2-glycols

Authors
Balashov, AL Danov, SM Chernov, AY Kvashennikov, AI
Citation
Al. Balashov et al., Synthesis of alkyl-substituted 1,3-dioxolanes by catalytic dehydration of 1,2-glycols, RUSS J G CH, 69(9), 1999, pp. 1418-1420
Citations number
12
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632 → ACNP
Volume
69
Issue
9
Year of publication
1999
Pages
1418 - 1420
Database
ISI
SICI code
1070-3632(199909)69:9<1418:SOA1BC>2.0.ZU;2-A
Abstract
The kinetics of the acid-catalyzed reactions of dehydration of ethylene gly col and 1,2-propylene glycol to respectively acetaldehyde and propionic ald ehyde and of condensation of the aldehydes with the glycols were studied. T he dependences of the apparent rate constants on temperature and catalyst c oncentration were determined. A mathematical model of the reactions studied was proposed.