Synthesis and properties of 5,6-dicyanobenzimidazole and porphyrazines derived from it

Citation
Ev. Kudrik et al., Synthesis and properties of 5,6-dicyanobenzimidazole and porphyrazines derived from it, RUSS J G CH, 69(8), 1999, pp. 1321-1324
Citations number
11
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632 → ACNP
Volume
69
Issue
8
Year of publication
1999
Pages
1321 - 1324
Database
ISI
SICI code
1070-3632(199908)69:8<1321:SAPO5A>2.0.ZU;2-Q
Abstract
4,5-Diaminophthalodinitrile was reacted with formic acid to synthesize 5,6- dicyanobenzimidazole which was used as starting material for preparing a me tal-free phthalocyanine with four annelated imidazole moieties, as well as its copper complex. The effect of the heteroannelation on the physicochemic al and spectral properties of the synthesized compounds was discussed.