Analysis of terrace width distributions on vicinal copper surfaces using the 'Wigner surmise': comparison with Gaussian approach

Citation
M. Giesen et Tl. Einstein, Analysis of terrace width distributions on vicinal copper surfaces using the 'Wigner surmise': comparison with Gaussian approach, SURF SCI, 449(1-3), 2000, pp. 191-206
Citations number
29
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
SURFACE SCIENCE
ISSN journal
00396028 → ACNP
Volume
449
Issue
1-3
Year of publication
2000
Pages
191 - 206
Database
ISI
SICI code
0039-6028(20000320)449:1-3<191:AOTWDO>2.0.ZU;2-P
Abstract
We have analyzed the terrace width distribution on a large number of Cu (10 0) and (111) vicinal surfaces using the standard Gaussian fit as well as by using an alternative analytical distribution, which comes from the perspec tive of fluctuation phenomena and is referred to as the generalized Wigner surmise. The chief motivation is to extract optimally the strength A of the elastic repulsion between steps. Both methods provide generally consistent estimates of the variance. We find the Wigner approach provides a Viable a lternative to the standard Gaussian approach. We review competing views on the proportionality constant relating A to the inverse square of the varian ce of a Gaussian fit; the experimental range of data seems to straddle the range over which various values are optimal. The previously suggested metho d for analyzing skewness proves unsatisfactory with actual data. By compari ng data for different temperatures and misorientations with predictions bas ed on scaling, we illustrate the difficulties of obtaining quantitative inf ormation about A. (C) 2000 Elsevier Science B.V. All rights reserved.