Synthesis, crystal structure, and magnetic properties of TbAl3Cl12

Authors
Patzke, GR Wartchow, R Urland, W
Citation
Gr. Patzke et al., Synthesis, crystal structure, and magnetic properties of TbAl3Cl12, Z ANORG A C, 626(3), 2000, pp. 789-792
Citations number
22
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
ISSN journal
00442313 → ACNP
Volume
626
Issue
3
Year of publication
2000
Pages
789 - 792
Database
ISI
SICI code
0044-2313(200003)626:3<789:SCSAMP>2.0.ZU;2-0
Abstract
TbAl3Cl12 was synthesized and the crystal structure was determined from sin gle crystal X-ray diffraction data for the first time, The compound crystal lizes trigonally in space group P3(1)12 with a = 10-49.8(1) and c = 1567.3( 2) pm. Terbium cations are located in quadratic antiprisms of chloride anio ns, Magnetic measurements were performed to study the interactions between Tb3+ and Cl-. Magnetic data were interpreted by ligand field calculations a pplying the angular overlap model.