ORGANOMETALLICS OF DIPHOSPHAZANES .10. DINUCLEAR GROUP-6 METAL-CARBONYL-COMPLEXES BRIDGED BY A CYCLODIPHOSPHAZANE IN ITS CIS OR TRANS FORM

Authors
REDDY VS KRISHNAMURTHY SS NETHAJI M
Citation
Vs. Reddy et al., ORGANOMETALLICS OF DIPHOSPHAZANES .10. DINUCLEAR GROUP-6 METAL-CARBONYL-COMPLEXES BRIDGED BY A CYCLODIPHOSPHAZANE IN ITS CIS OR TRANS FORM, Journal of the Chemical Society. Dalton transactions, (18), 1994, pp. 2661-2667
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
18
Year of publication
1994
Pages
2661 - 2667
Database
ISI
SICI code
0300-9246(1994):18<2661:OOD.DG>2.0.ZU;2-V
Abstract
Mononuclear Group 6 metal tetracarbonyl complexes containing a cyclodi phosphazane ligand, [PhNP(OC(6)H(4)Me-p)](2) (L), have been used as sy nthons to prepare homo- and hetero-bimetallic complexes in which the c yclodiphosphazane bridges the two metal centres in its cis or trans is omeric forms. The dimolybdenum complex [Mo-2(eta(5)-C5H5)(2)(CO)(4)(mu -L)] has also been synthesized. The trends in P-31 NMR chemical shifts and the structural features as revealed by X-ray crystallography are discussed.