2 DIFFERENT TERMINAL NITRATE BONDING MODES IN [FE2O(NO3)(4)(C7H7N3)(4)]

Authors
PLAKATOURAS JC BAKAS T HUFFMAN CJ HUFFMAN JC PAPAEFTHYMIOU V PERLEPES SP
Citation
Jc. Plakatouras et al., 2 DIFFERENT TERMINAL NITRATE BONDING MODES IN [FE2O(NO3)(4)(C7H7N3)(4)], Journal of the Chemical Society. Dalton transactions, (18), 1994, pp. 2737-2738
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
18
Year of publication
1994
Pages
2737 - 2738
Database
ISI
SICI code
0300-9246(1994):18<2737:2DTNBM>2.0.ZU;2-L
Abstract
Treatment of Fe(NO3)(3).9H(2)O with 1-methylbenzotriazole in EtOH-CH(O Et)(3) gave the unique, oxo-bridged complex [Fe2O(NO3)(4)(C7H7N3)(4)]; crystal structure and Mossbauer studies showed that the molecule has both bidentate and monodentate nitrates and possesses an S = 0 ground state, respectively.