Y2O3 has a relatively high dielectric constant (13-17) leading to several p
otential applications. In this work, pulsed-laser deposition was used to gr
ow epitaxial Y2O3 films on Si(111) substrates. Structural characterization
indicated two-dimensional growth without the formation of an amorphous inte
rfacial layer. Annealing in either Ar or O-2 was found to induce an O-2 dif
fusion reaction resulting in the formation of two interfacial amorphous lay
ers. Electrical characterization by capacitance-voltage and current-voltage
indicated that the as-grown samples were poor insulating films. Annealing
the samples improved the electrical performance by lowering leakage current
s and exhibiting inversion during capacitance-voltage testing. This epitaxi
al growth points toward the possibility of the heteroepitaxial growth of si
licon on insulator device structures. (C) 2000 American Institute of Physic
s. [S0003-6951(00)02613-9].