COMPARISON OF SHORT-RANGE INTERACTIONS IN NEMATIC LIQUID-CRYSTALS - AH-2-NMR STUDY OF 5CB-D(19) AS A SOLUTE

Previous studies using dideuterium as a solute have demonstrated the i mportance for orientation of the interaction between the solute molecu lar quadrupole moment and the average electric field gradient present in liquid crystals. With the aim of learning about additional orientat ional mechanisms, we have studied the temperature dependence of the H- 2-NMR spectra of the liquid crystal 5CB-d(19) as the solute in three l iquid crystal mixtures: 55 wt % 1132/EBBA, 56.5 wt % 1132/EBBA and 70 wt % 5CB/EBBA. In these mixtures, the contribution from the environmen t to the average electric field gradient at the H-2 nucleus of dideute rium is zero. The spectra of 5CB-d(19) in the mixtures 55 wt % 1132/EB BA and 56.5 wt % 1132/EBBA are equivalent, but are different from thos e in 70 wt % 5CB/EBBA. The spectra of 5CB in 55 wt % 1132/EBBA and 70 wt % 5CB/EBBA are analysed using two different models for the short ra nge potential, and parameters of the models are used to compare the po tentials in the different mixtures. For a given spectral splitting of the chain C-1 deuteron, the reduced short range potential is the same in all three mixtures studied. The spectral differences observed are a consequence of different nematic-isotropic phase transition temperatu res combined with the effect of trans/gauche-isomerization in the hydr ocarbon chain.