Single particle analysis of soil dust has been performed using aerosol time
-of-flight mass spectrometry. The presence of crustal elements is observed
in the mass spectra of individual particles. Aluminum and iron constitute t
he two most commonly detected cations. Other common cations observed in the
mass spectra of soil particles include sodium, magnesium, potassium, calci
um, titanium, and barium, and also lithium and lanthanide oxides which are
not detectable by conventional techniques such as X-ray fluorescence. Silic
ates make up the bulk of detected anions, although the presence of phosphat
e is also observed. Characteristic peaks in both the positive and negative
ion mass spectra enable us to identify individual dust particles in atmosph
eric samples and track chemically distinct dust particles in the atmosphere
with a temporal resolution of 15 min using aerosol time-of-flight mass spe
ctrometry. (C) 2000 Elsevier Science Ltd. All rights reserved.