Combustion of chromium powder in SHS reactors is examined. It is shown that
the maximum temperature in the central part of the powder samples is highe
r than the adiabatic temperature. The observed phenomenon is due to the non
-one-dimensionality of the combustion front. Overheating of the central par
t leads to melting of the product and a decrease in the degree of conversio
n, which should be taken into account in nitration of samples of large diam
eter.