Site-specific methylation of coordinated 1,2,4-triazoles: A novel route tosterically hindered Ru(bpy)(2) complexes

Authors
Fanni, S Murphy, S Killeen, JS Vos, JG
Citation
S. Fanni et al., Site-specific methylation of coordinated 1,2,4-triazoles: A novel route tosterically hindered Ru(bpy)(2) complexes, INORG CHEM, 39(6), 2000, pp. 1320
Citations number
14
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
39
Issue
6
Year of publication
2000
Database
ISI
SICI code
0020-1669(20000320)39:6<1320:SMOC1A>2.0.ZU;2-4
Abstract
A site-specific methylation of 1,2,4-triazolate rings in ruthenium(II) comp lexes Using OMe3+BF4- is reported. Interestingly methylation takes place pr eferentially at the most sterically hindered nitrogen atom of the coordinat ed triazole ring.