Solid state structures of [Ag-5(dppm)(4)(S2CC(CN)P(O)(OEt)(2))(2)][PF6] and Ag-4(dppm)(4)(S2CC(CN)P(O)(OEt)(2))(2): Variable coordination modes of 1,1-dithiolate to silver(I)

Authors
Liu, CW Liaw, BJ Wang, JC Keng, TC
Citation
Cw. Liu et al., Solid state structures of [Ag-5(dppm)(4)(S2CC(CN)P(O)(OEt)(2))(2)][PF6] and Ag-4(dppm)(4)(S2CC(CN)P(O)(OEt)(2))(2): Variable coordination modes of 1,1-dithiolate to silver(I), INORG CHEM, 39(6), 2000, pp. 1329
Citations number
34
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY
ISSN journal
00201669 → ACNP
Volume
39
Issue
6
Year of publication
2000
Database
ISI
SICI code
0020-1669(20000320)39:6<1329:SSSO[A>2.0.ZU;2-C
Abstract
A novel pentanuclear silver complex [Ag-5(dppm)(4)(S-2-CC(CN)P(O)(OEt)(2))( 2)][PF6], containing bridging dppm and 2-(diethoxyphosphinyl)-2-cyanoethyle ne-1,1-dithiolato ligands of which the 1,1-dithiolates exhibit an unprecede nted tetrametallic hexaconnective coordination pattern, is reported.