CONVECTIVE-TRANSPORT OVER THE CENTRAL UNITED-STATES AND ITS ROLE IN REGIONAL CO AND OZONE BUDGETS

We have constructed a regional budget for boundary layer carbon monoxi de over the central United States (32.5 degrees-50 degrees N, 90 degre es-105 degrees W), emphasizing a detailed evaluation of deep convectiv e vertical fluxes appropriate for the month of June. Deep convective v enting of the boundary layer (upward) dominates other components of th e CO budget, e.g., downward convective transport, loss of CO by oxidat ion, anthropogenic emissions, and CO produced from oxidation of methan e, isoprene, and anthropogenic nonmethane hydrocarbons (NMHCs). Calcul ations of deep convective venting are based on the method of Pickering et al. [1992a] which uses a satellite-derived deep convective cloud c limatology along with transport statistics from convective cloud model simulations of observed prototype squall line events. This study uses analyses of convective episodes in 1985 and 1989 and CO measurements taken during several midwestern field campaigns. Deep convective venti ng of the boundary layer over this moderately polluted region provides a net (upward minus downward) flux of 18.1 x 10(8) kg CO month(-1) to the free troposphere during early summer, assuming the June statistic s are typical. Shallow cumulus and synoptic-scale weather systems toge ther make a comparable contribution (total net flux 16.2 x 10(8) kg CO month(-1)). Boundary layer venting of CO with other O-3 precursors le ads to efficient free tropospheric O-3 formation. We estimate that dee p convective transport of CO and other precursors over the central Uni ted States in early summer leads to a gross production of 0.66-1.1 Gmo l O-3 d(-1) in good agreement with estimates of O-3 production from bo undary layer venting in a continental-scale model [Jacob et al., 1993a , b]. In this respect the central U.S. region acts as a ''chimney'' fo r the country, and presumably this O-3 contributes to high background levels of O-3 in the eastern United States and O-3 export to the North Atlantic.