Observations of the composition of inner source pickup ions in the solar wi
nd, from the Solar Wind Ion Composition Spectrometer on Ulysses, are presen
ted. The composition is similar to that of the solar wind and, in particula
r, contains volatile elements such as neon. These observations suggest stro
ngly, and perhaps conclusively, that inner source pickup ions result from s
olar wind particles that are embedded in dust grains and then released. Our
observations also suggest that inner source pickup ions may be an importan
t source for particles accelerated at shocks surrounding corotating interac
tion regions since the resulting composition will resemble that of the sola
r wind, as is observed. Mechanisms are described whereby inner source picku
p ions can be preferentially injected into die shock acceleration mechanism
.