A thiol compound with a long hydrocarbon chain was introduced into the deve
loping solution for a silver chloride DTR printing plate. It was found that
the hydrophobicity of physically developed silver area could be greatly im
proved. The higher the silver density and thiol concentration were, the gre
ater the hydrophobicity of the silver surface was. Raman and XPS study reve
aled that hydrophobization was caused by adsorption of the thiol compound o
n physically developed silver particles on the plate.