Z. Chvoj et al., Thermodynamic limits and kinetic probabilities during homogeneous nucleation in liquid Ag-Cu alloys, J NON-EQU T, 24(4), 1999, pp. 360-371
Novel kinetic phase diagrams for homogeneous nucleation during nun-equilibr
ium solidification of Ag-Cu alloys were evolved by stochastic modelling. Th
e allowable undercoolings and the composition of the primary nucleating pha
se at any cooling rate and liquid composition could be read from these diag
rams, The calculated values were found to lie within the thermodynamically
permissible limits determined through construction of non-isothermal metast
ability held diagrams.