Thermodynamic limits and kinetic probabilities during homogeneous nucleation in liquid Ag-Cu alloys

Citation
Z. Chvoj et al., Thermodynamic limits and kinetic probabilities during homogeneous nucleation in liquid Ag-Cu alloys, J NON-EQU T, 24(4), 1999, pp. 360-371
Citations number
28
Categorie Soggetti
Physics
Journal title
JOURNAL OF NON-EQUILIBRIUM THERMODYNAMICS
ISSN journal
03400204 → ACNP
Volume
24
Issue
4
Year of publication
1999
Pages
360 - 371
Database
ISI
SICI code
0340-0204(1999)24:4<360:TLAKPD>2.0.ZU;2-H
Abstract
Novel kinetic phase diagrams for homogeneous nucleation during nun-equilibr ium solidification of Ag-Cu alloys were evolved by stochastic modelling. Th e allowable undercoolings and the composition of the primary nucleating pha se at any cooling rate and liquid composition could be read from these diag rams, The calculated values were found to lie within the thermodynamically permissible limits determined through construction of non-isothermal metast ability held diagrams.