The total cross section, sigma, for electron capture by Na+ ions from orien
ted coherent elliptic states (CES) of Li with principal quantum number n =
25 was studied experimentally for impact perpendicular to the minor axis of
the elliptic orbit. The remaining geometrical parameters of the CES, which
are the eccentricity, e, and the angle, phi, between the major axis and th
e beam direction, were varied in the course of the experiments, as was the
reduced impact velocity upsilon(r) = n upsilon, where upsilon is the projec
tile velocity in atomic units. Several representative cuts were chosen with
in the parameter space (upsilon(r), e, phi) = (0.74-2.09, 0-1, 0-2 pi). The
velocity range includes the region of matching velocities (upsilon(r) simi
lar or equal to I) where a for given geometrical parameters attains its max
imum value and the high-velocity region where a is a strongly decreasing fu
nction of upsilon(r). The cross section depends sensitively on each geometr
ical parameter and the dependences change dramatically as upsilon, is varie
d. The spatial distribution of the CES apparently governs sigma in some reg
ion of parameter space (upsilon(r), e, phi) and in another the momentum dis
tribution prevails.