The Rayleigh scattering of the mixed-alkali glass system K2O-Na2O-MgO-SiO2
(KNMS) was investigated, both experimentally and theoretically. The lowest
Rayleigh scattering coefficient (38% of that for pure SiO2 glass) was obtai
ned when the glass composition was 22K(2)O-8Na(2)O-10MgO-60SiO(2) tin mol%)
. These values are equal to or less than the minimum values reported for th
e ternary sodium silicate glass Na2O-MgO-SiO2. The Rayleigh scattering caus
ed by concentration fluctuation was believed to have been reduced greatly i
n this KNMS glass, because the mobility of the alkali-metal ions was reduce
d by the mixed-alkali effect.