A. Jimenez-lopez et al., Insertion of porous chromia in gamma-zirconium phosphate and its catalyticperformance in the oxidative dehydrogenation of propane, LANGMUIR, 16(7), 2000, pp. 3317-3321
An expanded phase of acetate-hydroxide of Cr(III) intercalated into gamma-z
irconium phosphate has been isolated by refluxing a solution formed by chro
mium(III) acetate-hydroxide and gamma-zirconium phosphate, previously dispe
rsed in 1:1 water-acetone solution at 353 K. By calcination of this phase a
t 623 K under vacuum, an intercalated compound with a basal spacing of 1.73
nm and a surface area of 147 m(2) g(-1) was obtained. A temperature-progra
mmed reduction study reveals that this solid contains a little amount of ch
romium in high oxidation state. However, when the precursor is heated at 67
3 K, a collapsed structure with a low surface area was obtained. The insert
ed porous chromia in gamma-zirconium phosphate calcined at 623 K is active
in the oxidative dehydrogenation of propane at 623 K with 58% conversion an
d 10% of selectivity to propene. When this material is calcined at 823 Kin
air, it is also active in this reaction but only at high temperature, 823 K
being necessary to attain catalytic properties similar to those observed f
or the catalyst prepared at low temperature.