To test proposals for the origin of oxygen absorption bands in the vis
ible reflectance spectrum of Ganymede, the reflectance of condensed fi
lms of pure oxygen (O-2) and O-2-water mixtures and the evolution of O
-2 from the films as a function of temperature were determined, Absorp
tion band shapes and positions for oxygen at 26 kelvin were similar to
those reported for Ganymede, whereas those for the mixtures were slig
htly shifted. The band intensity dropped by more than two orders of ma
gnitude when the ice mixture was warmed to 100 keivin, although about
20 percent of the O-2 remained trapped in the ice, which suggested tha
t at these temperatures O-2 molecules dissolve in the ice rather than
aggregate in clusters or bubbles. The experiments suggest that the abs
orption bands in Ganymede's spectrum were not produced in the relative
ly warm surface of the satellite but in a much colder source. Solid O-
2 may exist in a cold subsurface layer or in an atmospheric haze.