Photoluminescence (PL) and PL excitation (PLE) measurements have been perfo
rmed in GaAs/AlxGa1-xAs biased double quantum well heterostructures. The re
combination of electrons, e, with holes, h, located in the same or in two a
djacent wells, has been investigated for different exciting power densities
, P, and temperatures, T. For increasing P or decreasing T, a sharp transit
ion from two gases of photoexcited electrons and holes, spatially separated
and confined in the two wells, to two two-dimensional (2D) liquids has bee
n observed. The gas-to-2D-liquid transition is evidenced by a strong screen
ing of applied biases and by major changes in the optical spectra. The phas
e diagram in the (P,T) plane of the e-h system has been determined. Time-re
solved FL, cw FL, and PLE in the presence of a magnetic field normal to the
quantum wells support the presence of e- and h-liquid phases in the two we
lls with a critical density equal to 8.8 x 10(10) cm(-2) and a binding ener
gy of 2.5 meV.