Thermochemistry of solution of natural porphyrins in benzene-electron donor mixed solvents

Authors
Chernova, OM Berezin, MB
Citation
Om. Chernova et Mb. Berezin, Thermochemistry of solution of natural porphyrins in benzene-electron donor mixed solvents, RUSS J PH C, 74(2), 2000, pp. 141-144
Citations number
8
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY
ISSN journal
00360244 → ACNP
Volume
74
Issue
2
Year of publication
2000
Pages
141 - 144
Database
ISI
SICI code
0036-0244(200002)74:2<141:TOSONP>2.0.ZU;2-B
Abstract
The solution of natural porphyrins of the protoporphyrin-IX group and their zinc metallocomplexes in mixed benzene-dimethyl formam ide, benzene-di met hylsulfoxide, and benzene-pyridine solvents was studied calorimetrically at 298.15 K in the whole composition range. The principal patterns of variati ons in the enthalpy characteristics of porphyrin-electron donor solvent int eractions depending on the structure of the porphyrin, the electronic struc ture of the metal ion, and the composition of the mixed solvent were determ ined.