Evidence for quasi-intramolecular acid-base reactions in solutions of transition metal ammine complexes

Authors
Kotai, L Horvath, T Szentmihalyi, K Keszler, A
Citation
L. Kotai et al., Evidence for quasi-intramolecular acid-base reactions in solutions of transition metal ammine complexes, TRANSIT MET, 25(3), 2000, pp. 293-294
Citations number
7
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
TRANSITION METAL CHEMISTRY
ISSN journal
03404285 → ACNP
Volume
25
Issue
3
Year of publication
2000
Pages
293 - 294
Database
ISI
SICI code
0340-4285(200006)25:3<293:EFQARI>2.0.ZU;2-6
Abstract
We have investigated the effect of temperature on the postulated quasi-intr amolecular acid-base reactions in aqueous solutions of Cu(NH3)(4)(MnO4)(2) and Ag(NH3)(2)ClO4. Pure ammonium permanganate and perchlorate were obtaine d above 5 degrees C and at room temperature, respectively, due to quasi-int ramolecular acid-base reactions.