Dehydrocondensation of organylsilanes giving Si-Si bonds

Authors
Pukhnarevich, VB Voronkov, MG Kopylova, LI
Citation
Vb. Pukhnarevich et al., Dehydrocondensation of organylsilanes giving Si-Si bonds, USP KH, 69(2), 2000, pp. 150-165
Citations number
220
Categorie Soggetti
Chemistry
Journal title
USPEKHI KHIMII
ISSN journal
00421308 → ACNP
Volume
69
Issue
2
Year of publication
2000
Pages
150 - 165
Database
ISI
SICI code
0042-1308(2000)69:2<150:DOOGSB>2.0.ZU;2-Z
Abstract
The data on catalytic dehydrocondensation of organylsilanes giving Si-Si bo nds are systematised and generalised. The mechanism and general features (t he influence of the nature of the reactants and the catalyst, the solvent, and the reaction conditions) of these reactions catalysed by transition met al cyclopentadienyl complexes are considered. Electrochemical and other met hods of dehydrocondensation of organylsilanes are discussed.