Orientation dependence of ferroelectricity in pulsed-laser-deposited epitaxial bismuth-layered perovskite thin films

Thin films of bismuth-layered perovskites such as SrBi2Ta2O9, Bi4Ti3O12, an d BaBi4Ti4O15.With preferred orientations were grown by pulsed laser deposi tion on epitaxial conducting LaNiO3 electrodes on single-crystalline (100) SrTiO3 or on top of epitaxial buffer layers on (100) silicon. A morphology and structure investigation by X-ray diffraction analysis, scanning probe m icroscopy, and scanning and transmission electron microscopy showed that th e films consisted of both c-axis-oriented regions and mixed (110)-, (100)-, and (001)-oriented regions. The regions with mixed orientation featured re ctangular as well as equiaxed crystalline grains protruding out of a smooth c-oriented background. A closer examination revealed that the regions with mixed orientation actually consisted of a c-axis-oriented sublayer growing directly on the epitaxial LaNiO3 electrode, on top of which the growth of either (110)-, (100)-, or (001)oriented grains took place. Macroscopic as w ell as microscopic measurements of the ferroelectric properties of regions with pure c-orientation and of regions with mixed orientations showed a cle ar relationship between their ferroelectric properties and their morphology and crystallographic orientation. In the regions with mixed orientation, t he films exhibited saturated ferroelectric hysteresis loops with well-defin ed remnant polarisation P-r and coercive field E-c. The regions having c-ax is orientation with a smooth surface morphology in contrast exhibited a lin ear P - E curve with no hysteretic behaviour for SrBi2Ta2O9 and BaBi4Ti4O15 and a weak ferreoelectric behaviour for Bi4Ti3O12 This clearly showed that the ferroelectric properties of bismuth-layered ferroelectric oxides depen ded on the crystalline orientation of the film and that the observed ferroe lectric hysteresis loops in SrBi2Ta2O9 and BaBi4Ti4O15 films were solely du e to the (100)- and (110)-oriented grains. The size of the (110)- and (100) oriented grains being of the order of 100 nm and spontaneous polarisation h aving been observed and switched in a controlled manner is a demonstration that ferroelectricity can exist in structures of submicrometer size. These results might have a technological impact due to the relevance of bismuth-l ayered ferroelectric oxides for the fabrication of non-volatile FeRAM memor ies.