Thermodynamic assessment of the Co-Ta system

Authors
Citation
Zk. Liu et Ya. Cheng, Thermodynamic assessment of the Co-Ta system, CALPHAD, 23(3-4), 1999, pp. 339-356
Citations number
31
Categorie Soggetti
Physical Chemistry/Chemical Physics","Chemical Engineering
Journal title
CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY
ISSN journal
03645916 → ACNP
Volume
23
Issue
3-4
Year of publication
1999
Pages
339 - 356
Database
ISI
SICI code
0364-5916(199909/12)23:3-4<339:TAOTCS>2.0.ZU;2-Z
Abstract
The phase equilibria and thermodynamic properties of the binary Co-Ta syste m were analyzed and a complete thermodynamic description of the binary syst em was obtained with the CALPHAD technique using a computerized optimizatio n procedure. The thermodynamic descriptions of pure Co and Ta elements were taken from the SGTE database. Based on the experimental data, six binary i ntermetallic compounds were considered. They are three Laves phases, mu pha se, theta phase and Co7Ta2 phase. The last two compounds are treated as sto ichiometric compounds. Good agreement was obtained between calculated resul ts and experimental data in the binary system.