Chemistry of M(allyl)(3) (M = Rh, Ir) compounds: structural characterization of tris(allyl)iridium complexes with phosphorus ligands

Authors
John, KD Salazar, KV Scott, BL Baker, RT Sattelberger, AP
Citation
Kd. John et al., Chemistry of M(allyl)(3) (M = Rh, Ir) compounds: structural characterization of tris(allyl)iridium complexes with phosphorus ligands, CHEM COMMUN, (7), 2000, pp. 581-582
Citations number
13
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
7
Year of publication
2000
Pages
581 - 582
Database
ISI
SICI code
1359-7345(2000):7<581:COM(=R>2.0.ZU;2-I
Abstract
While addition of phosphorus ligands such as P(OPh)(3) to Rh(allyl)(3) give s monovalent Rh(allyl)L-2, the iridium analog gives stable mixed sigma/pi-t ris(allyl) complexes, as evidenced by the structural characterization of mo no-, bi-, and tri-dentate ligand complexes.