The role of neighbouring group participation in TTF-mediated 'radical-polar crossover' reactions: trapping of aliphatic radicals by TTF+center dot

Authors
Bashir, N Murphy, JA
Citation
N. Bashir et Ja. Murphy, The role of neighbouring group participation in TTF-mediated 'radical-polar crossover' reactions: trapping of aliphatic radicals by TTF+center dot, CHEM COMMUN, (7), 2000, pp. 627-628
Citations number
11
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
7
Year of publication
2000
Pages
627 - 628
Database
ISI
SICI code
1359-7345(2000):7<627:TRONGP>2.0.ZU;2-U
Abstract
Trapping of secondary alkyl radicals with tetrathiafulvalenium tetrafluorob orate (TTF+.BF4-) leads to S-alkyltetrathiafulvalenium tetrafluoroborate sa lts; the solvolysis of such salts is critically dependent on the presence o f appropriately sited neighbouring groups.