Waste pyrolysis oil source of petrochemicals or just another type of fuel?

Citation
R. Rosemann et al., Waste pyrolysis oil source of petrochemicals or just another type of fuel?, FR ENV BULL, 9(3-4), 2000, pp. 137-143
Citations number
12
Categorie Soggetti
Environment/Ecology
Journal title
FRESENIUS ENVIRONMENTAL BULLETIN
ISSN journal
10184619 → ACNP
Volume
9
Issue
3-4
Year of publication
2000
Pages
137 - 143
Database
ISI
SICI code
1018-4619(200003/04)9:3-4<137:WPOSOP>2.0.ZU;2-N
Abstract
Pyrolysis oils are rich sources of aromatic hydrocarbons. A series of sampl es were taken from an industrial waste pyrolysis plant and analyzed for the ir content of BTX aromatics, EPA-PAH, PASH and phenols. Sampling took place during different phases of the pilot process (1984-87), the test phase of the commercial process (1996) and the current process (1997-98). Light and heavy oils from the pilot phase and the test phase of the commercial proces s consist primarily of aromatics and can be compared to coal tar. They cont ain 10-20% of BTX aromatics, 7-11% of naphthalene and 0.5-1.5% of methylnap hthalene, biphenyl, acenaphthylene, phenanthrene and pyrene, respectively. However, light oil from the current process mainly consists of aliphatic hy drocarbons plus a small amount of aromatics (10 % BTX aromatics, 1 % naphth alene). This material is more comparable with diesel fuel, but it still yie lds more than 0.005 % of benzo[a]pyrene which, according to German regulati ons, requires to be marked as carcinogenic material.