Electromagnetic geophysical methods, such as ground-penetrating radar (GPR)
, have proved to be optimal tools for detecting and mapping near-surface co
ntaminants. GPR has the capability of mapping the location of hydrocarbon p
ools on the basis of contrasts in the effective permittivity and conductivi
ty of the subsoil. At radar frequencies (50 MHz to 1 GHz), hydrocarbons hav
e a relative permittivity ranging from 2 to 30, compared with a permittivit
y for water of 80. Moreover, their conductivity ranges from zero to 10 mS/m
, against values of 200 mS/m and more for salt water. These differences ind
icate that water/hydrocarbon interfaces in a porous medium are electromagne
tically 'visible'. In order to quantify the hydrocarbon saturation we devel
oped a model for the electromagnetic properties of a subsoil composed of sa
nd and clay/silt, and partially saturated with air, water and hydrocarbon.
A self-similar theory is used for the sandy component and a transversely is
otropic constitutive equation for the shaly component, which is assumed to
possess a laminated structure. The model is first verified with experimenta
l data and then used to obtain the properties of soils partially saturated
with methanol and aviation gasoline. Finally, a GPR forward-modelling metho
d computes the radargrams of a typical hydrocarbon spill, illustrating the
sensitivity of the technique to the type of pore-fluid. The model and the s
imulation algorithm provide an interpretation methodology to distinguish di
fferent pore-fluids and to quantify their degree of saturation.