A. Pal et M. Bandyopadhyay, Photochemical formation of gold nanoparticles in aqueous Triton X-100 and its application for cyanide determination, I J CHEM T, 7(2), 2000, pp. 75-78
Pink coloured stable gold sol (lambda(max): 523 nm) has been prepared photo
chemically in aqueous Triton X-100 (TX-100) medium and used for spectrophot
ometric determination of cyanide. The colour of the sol decreases on cyanid
e addition and becomes colourless at the end point. Linear calibration is o
btained in the range of 0-26 ppm of cyanide concentration. The relative sta
ndard deviation for 8.65 ppm of cyanide is found to be +/-2.03%. The method
is simple, rapid and applied for real sample analysis.