Synthesis, properties, molecular structure and electron transfer salts of 13,13,14,14-tetracyano-1,6-and-1,8-pyrenoquinodimethanes (1,6-TCNP and 1,8-TCNP)

Authors
Sugiura, K Mikami, S Iwasaki, K Hino, S Asato, E Sakata, Y
Citation
K. Sugiura et al., Synthesis, properties, molecular structure and electron transfer salts of 13,13,14,14-tetracyano-1,6-and-1,8-pyrenoquinodimethanes (1,6-TCNP and 1,8-TCNP), J MAT CHEM, 10(2), 2000, pp. 315-319
Citations number
38
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science","Material Science & Engineering
Journal title
JOURNAL OF MATERIALS CHEMISTRY
ISSN journal
09599428 → ACNP
Volume
10
Issue
2
Year of publication
2000
Pages
315 - 319
Database
ISI
SICI code
0959-9428(200002)10:2<315:SPMSAE>2.0.ZU;2-9
Abstract
A guideline for a stable pi-extended Wurster type redox system is proposed and two new acceptor molecules having a pyrene pi-system were prepared and structurally characterised. 3,8-Bis(3',5'-di-tert-butylphenyl)-13,13,14,14- tetracyano-1,6-pyrenoquinodimethane gave an electron transfer complex with Mn(TPP) (H2TPP = m-tetraphenylporphyrin) containing a coordination bond.