Crystal structures and magnetic properties of ordered perovskites Ba(2)LnIrO(6) (Ln = lanthanide)

Authors
Wakeshima, M Harada, D Hinatsu, Y
Citation
M. Wakeshima et al., Crystal structures and magnetic properties of ordered perovskites Ba(2)LnIrO(6) (Ln = lanthanide), J MAT CHEM, 10(2), 2000, pp. 419-422
Citations number
10
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science","Material Science & Engineering
Journal title
JOURNAL OF MATERIALS CHEMISTRY
ISSN journal
09599428 → ACNP
Volume
10
Issue
2
Year of publication
2000
Pages
419 - 422
Database
ISI
SICI code
0959-9428(200002)10:2<419:CSAMPO>2.0.ZU;2-X
Abstract
The crystal structures and magnetic properties of ordered perovskites Ba(2) LnIrO(6) (Ln = lanthanide) are reported. They were determined to have monoc linic perovskite-type structures with space group P2(1)/n. Their magnetic s usceptibilities were measured from 2 to 350 K. Ba2CeIrO6 and Ba2PrIrO6 show antiferromagnetic transitions at 17 and 71 K, respectively. In these compo unds, the Ce and Pr ions are found to be in the tetravalent state from anal ysis of their crystal structures and magnetic susceptibilities.