Synthesis, structure and coordination chemistry of mono- and bis-heterocyclic-ferrocenyl derivatives

Authors
Isaac, CJ Price, C Horrocks, BR Houlton, A Elsegood, MRJ Clegg, W
Citation
Cj. Isaac et al., Synthesis, structure and coordination chemistry of mono- and bis-heterocyclic-ferrocenyl derivatives, J ORGMET CH, 598(2), 2000, pp. 248-253
Citations number
17
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
598
Issue
2
Year of publication
2000
Pages
248 - 253
Database
ISI
SICI code
0022-328X(20000402)598:2<248:SSACCO>2.0.ZU;2-W
Abstract
The heterocyclic-ferrocenyl derivatives, 1,1'-bis(5-phenanthridine)ferrocen e (1) and [Pd{(eta(5)-C5H5)Fe(eta(5)-C5H3(phenanthroline))Cl] (2), have bee n prepared and characterised by single-crystal X-ray analyses. These confir m that in 1 the substitution at the heterocycle is ortho to the nitrogen at om of the phenanthridine while for 2 artho-metallation of the ferrocenyl gr oup is observed in addition to chelation of the Pd(II) by the phenanthrolin e moiety. (C) 2000 Elsevier Science S.A. All rights reserved.