Synthesis and crystal structure of [U(eta-C8H8)](2)[mu-eta(4):eta 4-HN(CH2)(3)N(CH2)(2)N(CH2)(3)NH], a dinuclear compound with a bridging tetra-amideligand

Authors
Le Borgne, T Lance, M Nierlich, M Ephritikhine, M
Citation
T. Le Borgne et al., Synthesis and crystal structure of [U(eta-C8H8)](2)[mu-eta(4):eta 4-HN(CH2)(3)N(CH2)(2)N(CH2)(3)NH], a dinuclear compound with a bridging tetra-amideligand, J ORGMET CH, 598(2), 2000, pp. 313-317
Citations number
20
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
598
Issue
2
Year of publication
2000
Pages
313 - 317
Database
ISI
SICI code
0022-328X(20000402)598:2<313:SACSO[>2.0.ZU;2-Z
Abstract
The title compound was prepared by the transamination reaction of [U(COT)(N {SiMe3}(2))(2)] and H2N(CH2)(3)NH(CH2)(2)-NH(CH2)(3)NH2. The X-ray crystal structure reveals the shortest U-U distance [3.3057(9) Angstrom] ever obser ved in a molecular reserved compound. (C) 2000 Elsevier Science S.A. All ri ghts reserved.