Fluoroalkylated N-heterocyclic carbene complexes of palladium

Authors
Xu, LJ Chen, WP Bickley, JF Steiner, A Xiao, JL
Citation
Lj. Xu et al., Fluoroalkylated N-heterocyclic carbene complexes of palladium, J ORGMET CH, 598(2), 2000, pp. 409-416
Citations number
38
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022328X → ACNP
Volume
598
Issue
2
Year of publication
2000
Pages
409 - 416
Database
ISI
SICI code
0022-328X(20000402)598:2<409:FNCCOP>2.0.ZU;2-F
Abstract
Fluoroalkylated N-heterocyclic carbene complexes of palladium have been syn thesized from imidazolium salts and Pd(OAc)(2). The analogous carbene compl exes bearing long alkyl chains have also been prepared. The formation of th ese carbene complexes proceeds via an intermediate binuclear species, which has been isolated. Complexes such as these may find applications in cataly sis in supercritical CO2 (scCO(2)). (C) 2000 Elsevier Science S.A. All righ ts reserved.