The solubility in water and the partition coefficients, K, in soils samples
of residues of petroleum of different ages were determined using an organi
c cosolvent (methanol), and the solvophobic theory was applied for the inte
rpretation of results. The behavior of the residuals turned out to be depen
dent of the cosolvent fraction. The values of K's vary among 900 (Lkg(-1))
and 2,900 (Lkg(-1)) showing a general and marked increase for residues of i
ncreasing age. The determined parameters are useful for the modeling of env
ironmental impact in polluted soils.