Effect of substituents on the O-O bond rupture of different organic peroxides in toluene solution

Authors
Eyler, GN Canizo, AI Mateo, CM Alvarez, EE Nesprias, RK
Citation
Gn. Eyler et al., Effect of substituents on the O-O bond rupture of different organic peroxides in toluene solution, MOLECULES, 5(3), 2000, pp. 360-361
Citations number
3
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
MOLECULES
ISSN journal
14203049 → ACNP
Volume
5
Issue
3
Year of publication
2000
Pages
360 - 361
Database
ISI
SICI code
1420-3049(200003)5:3<360:EOSOTO>2.0.ZU;2-S
Abstract
The thermal decomposition reaction of cyclic organic peroxides was studied in toluene solution in a wide temperature range. The kinetic data show an i mportant substituent effect on the unimolecular homolysis of the O-O bond o f these molecules.