S(RN)1 and stille reactions: A new synthetic strategy

Authors
Corsico, EF Rossi, RA
Citation
Ef. Corsico et Ra. Rossi, S(RN)1 and stille reactions: A new synthetic strategy, MOLECULES, 5(3), 2000, pp. 431-432
Citations number
4
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
MOLECULES
ISSN journal
14203049 → ACNP
Volume
5
Issue
3
Year of publication
2000
Pages
431 - 432
Database
ISI
SICI code
1420-3049(200003)5:3<431:SASRAN>2.0.ZU;2-2
Abstract
The photostimulated reaction of Me3Sn- ion with mono, di and trichloro aren es in liquid ammonia gave very good yields of stannanes by the S(RN)1 mecha nism. These products reacted by a palladium-catalized cross coupling reacti on with halobenzenes to give phenylated products also in very goods yields. Similar yields can be obtained in one-pot reactions.