In this paper we describe a self-contained method for performing the spectr
al-imaging deconvolution of X-ray data on clusters of galaxies observed by
the ASCA satellite. Spatially resolved spectral studies of data from this s
atellite require such a correction, because its optics redistribute photons
over regions that are of comparable size to the angular scales of interest
in clusters. This scattering is a function not only of spatial position bu
t also of energy. To perform a correction for these effects we employ maxim
um-likelihood deconvolution of the image (within energy bands of 1 keV) to
determine the spatial redistribution, followed by a Monte Carlo energy reas
signment of photon energies with position to determine the spectral redistr
ibution. We present tests on simulated cluster data, convolved with the var
ious instrumental characteristics and the X-ray background, which show that
our methodology can successfully recover a variety of intrinsic temperatur
e profiles in typical observational circumstances. In Paper II (this issue)
we shall apply our spectral-imaging deconvolution procedure to a large sam
ple of galaxy clusters to determine temperature profiles.