Synthesis and study of compounds A(II)((BUO6)-U-V)(2)center dot nH(2)O (A(II) = Mn, Fe, Co, Ni, Cu, Zn; B-V=P, As)

Authors
Chernorukov, NG Suleimanov, EV Dzhabarova, ST Bardin, SV
Citation
Ng. Chernorukov et al., Synthesis and study of compounds A(II)((BUO6)-U-V)(2)center dot nH(2)O (A(II) = Mn, Fe, Co, Ni, Cu, Zn; B-V=P, As), RADIOCHEMIS, 42(1), 2000, pp. 15-32
Citations number
28
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RADIOCHEMISTRY
ISSN journal
10663622 → ACNP
Volume
42
Issue
1
Year of publication
2000
Pages
15 - 32
Database
ISI
SICI code
1066-3622(200001/02)42:1<15:SASOCA>2.0.ZU;2-A
Abstract
The synthesis conditions, composition, structure, and properties of the com pounds formed in the A(II)((BUO6)-U-V)(2)-H2O systems (A(II) = Mn, Fe, Co, Ni, Cu, Zn; B-V = P, As) were studied. The X-ray powder patterns and spectr oscopic and thermodynamic characteristics of the above compounds were obtai ned. The relations between their structure and physicochemical properties a nd features of the electronic structure of A(II) and B-V were considered.