The electrochemical study of the epoxidic films, electrodeposited on carbon steel

Citation
P. Drob et al., The electrochemical study of the epoxidic films, electrodeposited on carbon steel, REV CHIM, 50(11), 1999, pp. 777-782
Citations number
14
Categorie Soggetti
Chemical Engineering
Journal title
REVISTA DE CHIMIE
ISSN journal
00347752 → ACNP
Volume
50
Issue
11
Year of publication
1999
Pages
777 - 782
Database
ISI
SICI code
0034-7752(199911)50:11<777:TESOTE>2.0.ZU;2-8
Abstract
This paper presents the results of the electrochemical measurements regardi ng the epoxy films electrodeposited on carbon steel. Nyquist and Bode diagr ams were recorded for various immersion periods in 3% NaCl solution, using the open circuit potential method; their interpretation allows us to modell the corrosion process of carbon steel substrate under epoxy films with an electric equivalent circuit, which has two time constants. Epoxy film capac itance and resistance were monitored with immersion time emphasizing a low water permeability of films and respectively a reduced ionic transport in t hese films. Anodic polarization curves show low dissolution current densiti es and in consequence efficiency of the protective films does not decrease in time below 90%.