Thermal decomposition of sodium perborate in acetic and trifluoroacetic acids

Authors
Tolstyakov, VV Pevzner, MS Tselinskii, IV
Citation
Vv. Tolstyakov et al., Thermal decomposition of sodium perborate in acetic and trifluoroacetic acids, RUSS J G CH, 69(10), 1999, pp. 1544-1547
Citations number
12
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632 → ACNP
Volume
69
Issue
10
Year of publication
1999
Pages
1544 - 1547
Database
ISI
SICI code
1070-3632(199910)69:10<1544:TDOSPI>2.0.ZU;2-R
Abstract
Kinetic study of the decomposition of sodium perborate in acetic and triflu oroacetic acids by various titration procedures allowed evaluation of the d ecomposition rate constants for two groups of compounds with different type s of peroxide bonds. Decomposition of sodium perborate in trifluoroacetic a cid is a First-order reaction, and in the case of acetic acid reaction is c omplicated by formation of two types of compounds decomposing by different mechanisms.