Activity coefficients of nondissociated sulfurous acid species in concentrated solutions of sodium chloride and sulfite

Authors
Poltoratskii, GM
Citation
Gm. Poltoratskii, Activity coefficients of nondissociated sulfurous acid species in concentrated solutions of sodium chloride and sulfite, RUSS J G CH, 69(10), 1999, pp. 1553-1562
Citations number
20
Categorie Soggetti
Chemistry
Journal title
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
ISSN journal
10703632 → ACNP
Volume
69
Issue
10
Year of publication
1999
Pages
1553 - 1562
Database
ISI
SICI code
1070-3632(199910)69:10<1553:ACONSA>2.0.ZU;2-9
Abstract
The activity coefficients of nondissociated sulfurous acid species gamma(n) were determined from the experimental data for the systems NaCl-H2O-SO2 an d Na2SO3-H2O-SO2 at 298, 323, and 348 K on the basis of the previously reve aled constancy of the ratio gamma(+/-)(2)/gamma(n) congruent to Q. The simi lar concentration dependences of the logarithms of the activity coefficient s ln gamma(n) and ln gamma(+/-) are due to similar properties of the nondis sociated and ionic species of the electrolyte. The fulfillment of the Setch enow's rule was checked.