White port wines were made from Malvasia Fina and Rabigata grape musts that
were subjected to different combinations of skin contact and must oxygenat
ion. Increasing skin contact times increased the total phenolics, total hyd
roxycinnamoyl tartaric acids, total flavonoids and the formation of brown p
igments in the free-run musts. Both air exposure and hyperoxidation were ef
fective in lowering the concentration of hydroxycinnamoyl tartaric acids an
d flavonoids in newly fermented wines. Hyperoxidation seemed more effective
in removing these phenolic compounds and in reducing browning than air exp
osure in wines which had 8 and 25 h of skin contact. Phenolic compounds inc
reased with wood ageing, although the concentration of hydroxycinnamic acid
s were lower in all oxygenated wines than in the controls. However, must ox
ygenation prior to fermentation could not prevent further browning of the w
ines caused by the production of furans, and the increase of flavonoids dur
ing their ageing in wood. Increasing skin contact generally increased the t
otal monoterpene alcohol concentration for hyperoxidised wines, with some i
ncreases in air exposed wines. Total monoterpene alcohol concentration was
higher in hyperoxidised than in air exposed wines, made from musts with 8 a
nd 25 h of skin contact, after 18 months of wood ageing.