LIGHT-INDUCED ORIENTATION OF A LOW ABSORBING PHOSPHINE OXIDE AZO-DYE PMMA COPOLYMER - TOWARDS A TRADE-OFF BETWEEN TRANSPARENCY AND PHOTOINDUCED NONLINEARITY/
C. Fiorini et al., LIGHT-INDUCED ORIENTATION OF A LOW ABSORBING PHOSPHINE OXIDE AZO-DYE PMMA COPOLYMER - TOWARDS A TRADE-OFF BETWEEN TRANSPARENCY AND PHOTOINDUCED NONLINEARITY/, Chemical physics letters, 271(4-6), 1997, pp. 335-340
All-optical poling at a significant spectral distance from resonance i
s investigated in a new phosphine oxide ate-dye PMMA copolymer (PO-MA)
showing increased transparency with respect to Disperse Red 1 (DR1),
together with large second-order properties. Trade-off between all-opt
ical poling efficiency and resonant absorption of the non-linear polym
er is considered in detail. Consequences for the device conversion eff
iciency are discussed.