MAGNETIC EFFECTS OF PHOTOCHEMICALLY INDUCED REACTIONS IN DISPERSIONS OF AROMATIC KETONES IN POLYELECTROLYTE COMPLEXES OF POLYACRYLIC-ACID AND CATIONIC SURFACTANTS
Vb. Ivanov et Vv. Selikhov, MAGNETIC EFFECTS OF PHOTOCHEMICALLY INDUCED REACTIONS IN DISPERSIONS OF AROMATIC KETONES IN POLYELECTROLYTE COMPLEXES OF POLYACRYLIC-ACID AND CATIONIC SURFACTANTS, Colloid journal of the Russian Academy of Sciences, 59(3), 1997, pp. 295-297
The increase in light scattering during photolysis of benzophenone dis
persions in polyelectrolyte complexes on the basis of polyacrylic acid
and cetyltrimethylammonium bromide was found to be strongly affected
by a magnetic field. These effects are one or two orders of magnitude
stronger than the primary magnetic effects, which are measured by the
influence of the held on the accumulation of the products formed durin
g photochemical reduction of the ketone. Analysis of light scattering
spectra and the dependence of the magnetic effect on the sample proper
ties and irradiation conditions shows that a magnetic field accelerate
s structural transitions in micron-sized particles, thus increasing th
eir refractive index.